Title : Electrochemolomic methodology for plant taxonomy
Abstract:
A methodology for characterizing vegetal taxonomic groups, based on microextraction-assisted voltammetry of immobilized particles applied to microsamples of vegetal matter is described. It is based on recording the voltammetric response of microparticulate films deposited from ethanol, acetone, etc. extracts of different parts of plants put in contact with aqueous electrolytes. The obtained voltammetric profiles, associated to electroactive metabolites in vegetal matter, define an electrochemolomic response which can be applied for discriminating different taxonomic groups using bivariant and multivariant chemometric techniques. Application of the reported methodology for a set of species of different orders suggests the possibility of correlating electrochemical data with phylogenetic trees (see Domenech-Carbo et al. Electrochemistry-based chemotaxonomy in plants using the voltammetry of microparticles methodology. New Journal of Chemistry, 2015, 39, 7421-7428; Domenech-Carbo et al. Access to phylogeny from voltammetric fingerprints of seeds: the Asparagus case. Electroanalysis, 2017, 29, 643-650).